Physical Properties of Polymers (Polymer Physics: Statics) 

Gregory Beaucage
MWF 11-12
Baldwin 641


20-MTEN-634

Office:
492 Rhodes Hall
556-3063
beaucag@uc.edu

Polymer Science Graduate Curriculum at UC
(Undergraduate Materials Curriculum)

Polymer Physical Properties gives students a basic level of knowledge of the terminology and mathematics involved in the physical understanding of polymers. Most of the topics deal with post-1970 concepts involving the static's of polymeric materials. The course is intended for graduate students who need to gain a cursory understanding of modern approaches to polymer physics. The course will use Strobl's text The Physics of Polymer (2007) chapters 1 to 4, 8, 9 and the appendix. Introductory courses in polymers and thermodynamics are necessary for the course. The course requires a basic understanding of calculus and statistical mathematics such as should be covered in a "traditional" undergraduate science or engineering degree.

This course is designed as a required graduate course but undergraduates and graduate students outside of Chemical and Materials Engineering often take this class. For undergraduates a letter grade boost is given (and A is an 80 or higher for undergraduates) and for non-CME majors who take this course as an elective some informal grading concessions are usually made on a case-by-case basis. Generally this course involves a significant amount of work compared to other classes.

Course Logistics
Location/Time

Winter 2008: Graduate
(Undergrad Elective)
20 MTEN 634 001
MWF 11:00 to 11:50
641 Baldwin

Prof. Greg Beaucage
492 Rhodes (410 Rhodes Lab)
556-3063 (5152)
beaucag@uc.edu
Directions

=>To Beaucage Homepage

Comments/Corrections


To Current Grade Sheet

To Required Books
Evaluations

Spring 2004 *Problem
Spring 2003
Spring 2002
Spring 2001
(College Link)
Spring 2001

(Local Link) ***

Quizzes

Quizzes PDF 2000 (Dynamics Quizzes):  Quiz 7; Quiz 8; Quiz 9; Final
Quizzes PDF S2001:  Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8; Quiz 9
Quizzes PDF S2002:  Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8; Quiz 9; Quiz 10; Final Exam
Quizzes PDF S2003:  Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8, Quiz 8 Question1.xls, Quiz 8 Question2.xls, Quiz 9; Quiz 10
Quizzes PDF S2004
Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8; Quiz 9; Quiz 10; Final
Quizzes S2005:  Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8; Quiz 9; Final
Quizzes S2006: Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8; Quiz 9; Final (All Quizes 1 to 9)
Quizzes S2007: Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8; Final
Quizzes W2008: Quiz 1; Quiz 2; Quiz 3; Quiz 4; Quiz 5; Quiz 6; Quiz 7; Quiz 8; Quiz 9; Final

 

Useful Links for Critical Reviews:
Citation Search for UC/Ohiolink
Electronic Journals (online) for Ohio Link

Optional Projects
Project 1: Simulation of Random Walks

(Shape Distribtion Function of Solc B; A)
Project 1B:  More Random Walk Things
Project 2:  Ising Model Simulation using Metropolis Method
Metropolis web page (You can just search Google for Metropolis)
Project 3:  Dumbell Model Simulation
Monte Carlo


UC Santa Cruz Class On Simulation
Simon Fraiser Univ. Simulation Class
Oregon State Class
Dayton Correlation Function (at End)
Scott Korfhagen (MS UC 2007) Executables Project 1 and 2
Jessica Kangas 100 Random Walks in a Mov file


    
Class Notes (some errors in notes please follow Strobl Text which is mostly correct)
Syllabus.html  

Properties of an isolated polymer molecule.pdf
                                            (PrIsPmMol.html)
----Topological Model (1/19/08)
----Brownian Motion
---------****Chandrasekhar's Seminal Review of
                          Stochastic/Markovian Processes

---------Einstein 1905 Paper on Brownian Motion
---------Brownian Motion Simulation, Another Brownian 080123
---------Gaussian Plot Derivation of Gaussian Moments, Question
----Why doesn't thermodynamics apply at the micron to nanometer scale?
----
Persistence.html (2007)
----Persistence Length/RISM.pdf
----Flory II Persistence
-----Persistence/Kuhn Definitions, Boal: Simon Fraiser Univ.
----------Statistical Physics of Chains
----Protein Structure
Hydrodynamic Radius.pdf
Radius of Gyration.pdf
----Derivation of Guinier's Law (Gaussian Approach)
----Radius of Gyration Feigin Svergun Book
----Convolution:Correlation:Fourier Transform
Dynamic Light Scattering
----------Hydrodynamic radius.html Link
----------Hydrodynamic Radius for a Rod.pdf
Flory Krigbaum Prediction Plots
----Coffee Cup and Doughnut (from Wikipedia)
----Diffusion of Space Junk
Thermal Blob Notes.html

Interesting Persistence Web Page UPenn
Persistence with branching.pdf; Experimental Persistence with SCB
Anrun Paper
Persistence Pittsburgh; Wikipedia Persistence
Brownian Motion Simulation; Chain Dynamics applet
--------Ising Simulation Applet
--------General information on Ising Model
Background:  Wikipedia Entropy (Should be fully understood)
                      Classical and Statistical Thermodynamics Class (Section 2)
Thermal Blob Notes.pdf
Fractal/Elastomer Mechanics
Witten Paper
Partition Function Definition
Excluded Volume in Gasses (the original Exc. Vol.)

Concentrated solutions and melts.html
----------Electrostatic screening
More on Screening Analogy
---Tensile Blob
-----Pincus Paper
-----Sukumaran Paper
---- Osmotic Pressure from Kinetic Theory of Gasses
----Gas Mixing
----Expaned Coil Osmotic Pressure.html
----Strobl Osmotic Plotsaf
----Polymer Blends.pdf
----Spinodal Decomposition and other Morphological Consequences
----------Movie of Spinodal Decomposition
----------Better Movies of Spinodal and Ostwald Ripening
Hashimoto Spinodal Paper
----More RPA Notes '03

----Yamakawa Book (His web page http://www.molsci.polym.kyoto-u.ac.jp/archives/redbook.pdf)

Cahn-Hilliard vs Gibbs-Thompson

Concentrated solutions and melts.pdf
----------Electrostatic screening
More on Screening Analogy
---Tensile Blob
-----Pincus Paper
-----Sukumaran Paper
---- Osmotic Pressure from Kinetic Theory of Gasses
----Gas Mixing
----UCLA che212 (http://www.polysep.ucla.edu/
            che212/Notes/MW%20and%20branching.pdf)
----French Osmotic Pressure/FH
----Osmotic Pressure Oxford
                  (More Thomas Oxford)
----Expanded Coil Osmotic Pressure.pdf
----Osmotic Pressure from FH Eqn
       http://www.ias.ac.in/initiat/sci_ed/resources/chemistry/Collig.pdf
----ZimmPlot IAS
----Ideal Gas DG ; Ideal Gas Mixing
----Polymer Blends.pdf
----
Spinodal Decomposition and other Morphological Consequences
----------Movie of Spinodal Decomposition
----------Another Movie for Spinodal
Plots of Flory Huggins Equation:
----------N = 1 Variable Chi from 0 to 4
----------N = 1 Chi = 2.5
----------Chi = 2.5 Variable N
----------Chi = 0 Variable N
----------Combinatorial PVME Phase Separation NIST
Hashimoto Spinodal Paper
----More RPA Notes '03
Sheffield Notes
---(http://www.shef.ac.uk/physics/people/rjones/PDFs/PHY369/Section2.pdf)
Flory Rehner Theory from Flory I.pdf; Degennes c* Theorem;
                         Sukumaran GTB Theorem

Dynamics and Linear Response Theory
      Wikipedia Impulse Response
      Electrical Dynamics from Germany (Local)
      Statistical Mechanics From NYU
      MIT Linear Resonse (Electrical)
      Buffalo Non-Equil Mol Dynamics
Strobl 2 Dynamic Constants
Lodge Liquid.pdf (Lodge Liquid.html)
Science 2004 Dynamics

Debye relaxor and Modes of Relaxation
Protein Glass Transition.pdf Review
Dissipation of Fluctuations
Rouse and Dumb-bell Models:
----Dumb-bell Model.html
---------
Dumb bell Italy , Paper on DNA using Dumb Bell
----Rouse Model.html
Entanglements.html, Paper Defining "Entanglement"
Hydrodynamic Interactions.html Underconstruction

Dynamics and Linear Response Theory
Debye relaxor and Modes of Relaxation
Dissipation of Fluctuations
Lodge Liquid.pdf

Rouse Model.pdf
Entanglements.pdf
Hydrodynamic Interactions.pdf Underconstruction

Lagrangian and Hamiltonian (Arizona)

Rubber Elasticity.html
-----(Background on Continuum Mechanics.pdf)
-----Rubber Elasticity for Mech of Mat.
Polymer gels.html
Rubber Elasticity.pdf
-----(Background on Continuum Mechanics.pdf)
-----Rubber Elasticity for Mech of Mat.pdf
Polymer gels.pdf

What is a critical review? (html); What is a critical review? (pdf)
From S01 Some Information is outdated: How to Write a Critical Review.pdf
From S01 Some Information is outdated: More on Critical Review.pdf
Example Critical Review (2005)

Textbook:

  1. "The Physics of Polymers, 2'nd Edition, Concepts for Understanding Their Structure and Behavior" G. Strobl, Springer Press 1997 (3'rd Ed. 2007).
  2. "Introduction to Polymer Physics" M. Doi, Clarendon Press 1996. Available at Amazon.com for $25 search Masao Doi
  3. Class Notes Posted on the Web at:
    http://www.eng.uc.edu/~gbeaucag/BeaucageResearchGroup.html
  4. "Scaling concepts in polymer physics" P. G. de Gennes 1979.
  5. "The theory of polymer dynamics" Oxford University Press, 1986.
  6. "Principles of polymer chemistry." P. J. Flory, 1953.
  7. "Polymer Chemistry, The Basic Concepts", Paul C. Hiemenz, Marcel Dekker 1984/2005.
  8. note
    Berlin html Notes Very Similar to This Course
    note
  9. A Math review page that may be useful for some.
  10. Book on Neutron Scattering and good sections on polymers by Boualem Hammouda of NIST (UC Link)


Grades

Only whole grades will be given: A = 90.0 to 100; B = 80.0 to 89.9; C = 70.0 to 79.9; D = 60.0 to 69.9

Critical Reviews are generally due 2 weeks after the quiz to be replaced but all Critical Reviews must be turned in the last Wednesday of Classes May 30 by 5pm in 492 Rhodes. Senior undergraduates will be required to write a critical review for the final which is due Friday June 1 at 5 pm in 492 Rhodes.

Final Exam:  TAB (or as long as you want) p.m. TBA valued at 3 quizzes.  

 

 


=>To Beaucage Homepage
*Problem:  Course evaluations were taken but are not yet available from the college (as of 10/2004)
**Problem:  Evaluations were taken but were lost by college.
***Problem:  Only 3 responses are logged by college but students reported full response from class.

Copyright (c) 2007,2006,2005,2004,2003,2002,2001,1998

Polymer Properties page, designed by / G. Beaucage / beaucag@uc.edu
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 

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